江蓠中类菌孢素氨基酸(MAAs)成分分析及提取研究     

金宁宁  张朝辉  李八方 《海洋科学》2012,36(3):74-80

利用高效液相色谱技术对江蓠(Gracilariaceae)中类菌孢素氨基酸(MAAs)进行了分析,并采用响应面分析法对MAAs物质的提取工艺进行优化研究。根据正交旋转组合试验设计原理,采用四因素五水平的响应面分析法,依据回归分析确定各因素的显著程度及最优工艺条件。结果表明,江蓠中MAAs的主要成分为porphyra-334;提取温度、浸提时间、甲醇浓度及液固比为影响MAAs物质提取的显著因素。通过多元二次回归拟合模型响应面分析,得到最优工艺条件:提取温度48.12℃,液固比34∶1,甲醇浓度25%,浸提时间1.85 h,优化条件下预测提取率为4.943 mg/g;试验值为4.893 mg/g,试验值与预测值吻合较好,响应面回归模型的准确性得到验证。  相似文献   

松辽盆地徐家围子断陷深层异常高孔带分布特征与成因分析   总被引：2，自引：0，他引：2  

孟元林  刘文慧  孟凡晋  梁伯勋  王建伟  潘雪梅  田伟志  王维安  丁桂霞  周振东  肖丽华 《古地理学报》2011,13(1):75-84

为了解松辽盆地低孔低渗背景下优质储集层的形成和分布,文中应用岩心实测孔隙度、测井孔隙 度以及铸体薄片等资料,研究了松辽盆地徐家围子断陷异常高孔带的分布特征及其成因。结果表明,松辽盆地 北部纵向上发育3个异常高孔带（ⅰ-ⅲ）, 其深度分布范围分别为600~2350m、2500~3500m、3600~4400m,对应的孔隙度分别为12%~35%,6%~28%,5%~20%。第ⅰ高孔带主要发育在中浅层, 主要由Ⅰ、 Ⅱ型干酪根形成的有机酸溶蚀砂岩储集层形成;第ⅱ、ⅲ异常高孔带发育在深层,主要由Ⅲ型干酪根产生的大 量有机酸溶蚀砂砾岩储集层和火山岩储集层形成,大气水淋滤作用也有一定贡献。此外,裂缝和岩相对徐家围 子断陷深层异常高孔带的形成具有特别重要的意义。  相似文献   

城市热岛效应下浅层土中混凝土的酸腐蚀试验研究   总被引：1，自引：0，他引：1  

卢毅  施斌  刘瑾  顾凯  唐朝生  高磊 《地震学刊》2011,(3):241-246,274

针对城市热岛效应引起城区浅层土地温场升高这一观测结果,采用室内快速模拟试验方法,对城区酸性土壤腐蚀混凝土材料的温度效应开展了试验研究。试验研究了在温度为5℃、20℃和40℃条件下,混凝土试样在酸浓度分别为0%、5%和10%的沙土介质中放置30d、90d后的抗压强度变化规律,并对混凝土试样在腐蚀过程中的腐蚀系数变化规律和微观机理进行了分析;最后,对南京城区热岛效应环境下浅层土中混凝土材料酸腐蚀的强度变化规律进行了分析。试验结果表明,在同一腐蚀浓度下,混凝土试样抗压强度的下降速度随着温度的升高而不断加快,其腐蚀系数也随着温度的升高而不断增大;腐蚀介质的浓度越大,环境温度对混凝土腐蚀系数的影响就越明显;在温度为40℃、硫酸浓度为10%的沙土中放置30 d后,混凝土的腐蚀系数K达到45.21%,约是在5℃条件下腐蚀系数的2倍,相当于环境温度每上升1℃,混凝土腐蚀系数平均增加0.64%。该研究成果对于减轻城市热岛效应对岩土工程的影响具有重要意义。  相似文献   

Performance of A Combination Process of UV/H2O2/Micro‐Aeration for Oxidation of Dichloroacetic Acid in Drinking Water     

WenHai Chu  N. Y. Gao  Y. Deng 《洁净——土壤、空气、水》2009,37(3):233-238

The decomposition of dichloroacetic acid (DCAA) in water using a UV/H₂O₂/micro‐aeration process was investigated in this paper. DCAA cannot be removed by UV radiation, H₂O₂ oxidation or micro‐aeration alone, while UV/H₂O₂/micro‐aeration combination processes have proved effective and can degrade this compound completely. With initial concentrations of about 110 μg/L, more than 95.1% of DCAA can be removed in 180 min under UV intensity of 1048.7 μW/cm², H₂O₂ dosage of 30 mg/L and micro‐aeration flow rate of 2 L/min. However, more than 30 μg/L of DCAA was left after 180 min by UV/H₂O₂ combination process without micro‐aeration with the same UV intensity and H₂O₂ dosage. The effects of applied UV radiation intensity, H₂O₂ dose, initial DCAA concentration and pH on the degradation of DCAA have been examined in this study. Degradation mechanisms of DCAA with hydroxyl radical oxidation have been discussed. The removal rate of DCAA was sensitive to operational parameters. There was a linear relationship between rate constant k and UV intensity and initial H₂O₂ concentration, which indicated that a higher removal capacity can be achieved by improvement of both factors. A newly found nitrogenous disinfection by‐product (N‐DBP)‐DCAcAm, which has the potential to form DCAA, was easier to remove than DCAA by UV/H₂O₂ and UV/H₂O₂/micro‐aeration processes. Finally, a preliminary cost comparison revealed that the UV/H₂O₂/micro‐aeration process was more cost‐effective than the UV/H₂O₂ process in the removal of DCAA from drinking water.  相似文献   

Biorefining of Green Biomass – Technical and Energetic Considerations     

Birgit Kamm  Petra Schönicke  Michael Kamm 《洁净——土壤、空气、水》2009,37(1):27-30

The development of biorefineries is the key for access to an integrated production of food, feed, chemicals, materials, goods, fuels and energy of the future. This communication considers an integrated green biorefinery combined with today's production of feed in the green agriculture. Special attention is given to the combination of physical and biotechnological processes for the production of proteins as well as platform chemicals such as lactic acid and lysine. Mass and energy flows (steam and electricity) are given for the biorefining of green biomass to produce platform chemicals, proteins, feed and biogas from residues.  相似文献   

酸性、碱性以及热处理环境下泡桐花粉保存实验研究     

郭中领  许清海 《干旱区地理》2009,32(3)

在实验室条件下对泡桐花粉进行热处理、酸处理、碱处理.观察发现,泡桐花粉十分耐酸、碱和高温.用蒸馏水煮沸花粉混合液1～10 h,花粉几乎无变化;用5%氢氧化钠溶液煮沸泡桐花粉1～5小时,部分花粉外壁变得略为粗糙.用30%和40%的氢氧化钠溶液对其煮沸达3小时,个别花粉壁轻微破裂;用50%硫酸溶液煮沸泡桐花粉达3小时,镜下观察一少部分花粉碳化变黑,个别花粉壁破坏.整个实验中几乎没有花粉壁破坏严重,观察到的极个别破坏程度较大的花粉也不能断定是上述处理造成的.花粉的破坏和蚀变机理有待进一步研究.  相似文献   

Adsorption kinetics, isotherm, and thermodynamic studies of adsorption of pollutant from aqueous solutions onto humic acid   总被引：1，自引：0，他引：1  

YaJun Wang  HongLang Xiao  Fang Wang 《寒旱区科学》2009,1(4):0372-0379

In the present study,humic acid was used as an adsorbent for the investigation of the adsorption kinetics,isotherms,and thermo-dynamic parameters of hexavalent chromium from aqueous solution at varying pH,temperatures,and concentrations.Adsorption isotherms and equilibrium adsorption capacities were determined by the fittings of the experimental data to three well-known iso-therm models:Langmuir,Freundlich,and Redlich-Peterson.The results showed that the Langmuir and Redlich-Peterson models appear to fit the adsorption better than did the Freundlich adsorption model for the adsorption of chromium onto humic acid.The equilibrium constants were used to calculate thermodynamic parameters such as the change of free energy,enthalpy,and entropy.The derived adsorption constants (logaL) and their temperature dependencies from Langmuir isotherm have been used to calculate the corresponding thermodynamic quantities such as the free energy of adsorption,heat,and entropy of adsorption.The thermo-dynamic data indicate that Cr (VI) adsorption onto humic acid is entropically driven and characterized by physical adsorption.  相似文献   

太湖典型植物氨基酸组成特征及其对水环境的影响   总被引：1，自引：0，他引：1  

刘丹  白画画  朱元荣  林樱  吴丰昌 《湖泊科学》2015,27(1):119-127

在太湖两个不同湖区(东太湖和贡湖)各选择了8种不同类型的典型水生植物和1种陆生植物全株作为研究对象,采用邻苯二甲醛柱前衍生-反相高效液相色谱法对其中15种氨基酸的组成特征进行了分析,并探讨了植物来源氨基酸对湖泊水环境的影响.结果表明东太湖区域植物体中总可水解氨基酸(THAAs)的平均含量为861.6±182.96μmol/g,贡湖区域植物体中THAAs平均含量为700.0±232.3μmol/g;不同类型植物体中THAAs的含量大小依次为:沉水植物、浮叶植物挺水植物陆生植物;其中天冬氨酸、谷氨酸、精氨酸、丙氨酸和赖氨酸是THAAs的主要组成部分,这5种氨基酸的摩尔浓度占氨基酸总量的50%以上;太湖植物中THAAs所含的氮元素对植物总氮的贡献在30.7%~94.7%之间,是植物体氮元素的主要组分,也是内源氮输入的主要来源.东太湖区域采集的植物样品中各氨基酸的浓度比例与东太湖水体氨基酸组成差异较大,但与沉积物氨基酸组成较吻合,表明东太湖植物来源的有机质和氨基酸是沉积物中有机质和氨基酸的重要来源.  相似文献   

Amino acid geochronology of gastropod-bearing Pleistocene units in Illinois,central USA     

《Quaternary Geochronology》2015

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广州地区蔬菜生产基地有机污染物含量状况及分布     

游远航 《吉林大学学报(地球科学版)》2015,45(4):1205-1216

为了解广州地区蔬菜基地有机污染物的分布情况,选取了6个代表性基地进行调查采样,测试分析了表层土壤、蔬菜及灌溉水中15种邻苯二甲酸酯(PAEs)化合物、16种多环芳烃(PAHs)化合物和19种有机氯农药(OCPs)化合物的质量分数及质量浓度.结果表明:在15种PAEs化合物的总质量分数(w(ΣPAEs))中,土壤样品为158.0~4 321.0 ng/g,蔬菜样品为1 134.0~48 576.0 ng/g;水样中15种PAEs化合物的总质量浓度(ρ(ΣPAEs))为632.0~14 271.0 ng/L;就单个化合物而言,以DiBP、DBP、DEHP三种污染物为主,其三项之和占所有PAEs质量分数的97.5%~99.1%;在16种PAHs化合物的总质量分数(w(ΣPAHs))中,土壤样品为28.48~1 121.96 ng/g,蔬菜样品为238.09~1 000.61 ng/g;水样中16种PAHs化合物的总质量浓度(ρ(ΣPAHs))为338.21~1 239.78 ng/L;在19种OCPs化合物的总质量分数(w(ΣOCPs))中,土壤为0.04~71.28 ng/g,蔬菜为1.08~9.18 ng/g.总体上看,各基地土壤中DBP质量分数均超标,多环芳烃类在灵山、花东、黄埔菜地土壤中存在轻微污染,有机氯农药均未出现污染.  相似文献